We never got the log or any additional information, so we were unfortunately unable to tell why those recipients were rejected.
However, if you are facing a similar issue, the original answer still applies. To determine error status codes and error messages for rejected recipients, call SmtpException's GetRejectedRecipients() method. It returns an array of SmtpRejectedRecipient objects - one for each recipient. Alternatively, create a communication log that should make it possible to tell what is going on and why the recipients were rejected.